Lewis acid-mediated transformations of 5-acyl-N-fluoroalkyl-1,2,3-triazoles to cyclopentenones, indenones, or oxazoles
Lukáš Janecký,
Petr Beier
Abstract:2-N-Substituted indenones, cyclopentenones or 4-carbonyl oxazoles are prepared from 5-acylated N-fluoroalkyl substituted 1,2,3-triazoles and Lewis acids.
A new synthetic approach towards trifluoromethylated heterocycles, based on the reaction of 5-acylated N-fluoroalkyl substituted 1,2,3-triazoles under microwave heating, proceeding via ketenimines is presented.
A new synthetic approach towards trifluoromethylated heterocycles, based on the reaction of 5-acylated N-fluoroalkyl substituted 1,2,3-triazoles under microwave heating, proceeding via ketenimines is presented.
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