Lead(iv) acetate: intriguing reactivity profile

Khan, Faiz Ahmed; Sudheer, Ch.; Soma, Laxminarayana

doi:10.1039/b708268a

Cited by 7 publications

(1 citation statement)

References 27 publications

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“…It has several applications in organic synthesis viz. synthesis of fullerenyl esters, 1 formation of spirocyclic tetrahydrofuran derivatives, 2 diastereoselective aziridination of enones, 3 C-N bond formation 4 and several others. Very interesting multistage heterodomino trans-formation, 5 oxidative fragmentation of homoallylic alcohols, 6 and an oxidative cleavage of allyl alcohols induced by the O 3 /Pb(OAc) 4 , 7 oxidative decyclization in the synthesis of 6-hydroxycarvone derivatives 8 have been more recently reported.…”

Section: Introductionmentioning

confidence: 99%

Lead(IV) Acetate

Yadav

2012

Synlett

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This feature focuses on a reagent chosen by a postgraduate, highlighting the uses and preparation of the reagent in current research 1262 spotlight Lead(IV) Acetate Compiled by Rammohan R. Yadav Rammohan R. Yadav was born in Warangal, Andhra Pradesh, India in 1986. He received his B.Sc. (2006) and M.Sc. in Organic Chemistry ( 2009) from the Kakatiya University, Warangal, India. Currently, he is working towards his Ph.D. under the guidance of Dr. Ram A. Vishwakarma and co-guidance of Dr. Sandip B. Bharate at the Indian Institute of Integrative Medicine (IIIM-CSIR), Jammu, India. His research interests focus on the medicinal chemistry of natural products and the development of novel synthetic methodologies for the modification of natural products of biological significance.

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Section: Introductionmentioning

confidence: 99%

Lead(IV) Acetate

Yadav

2012

Synlett

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ChemInform Abstract: Lead(IV) Acetate: Intriguing Reactivity Profile.

2008

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Diastereoselective Synthesis of Spirocyclic Dihydrofurans and 1‐Oxaspiro[4.5]decan‐6‐one Derivatives from Norbornyl α‐Diketones

Mahadevegowda¹,

Khan

2014

Eur J Org Chem

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A diastereoselective zinc‐mediated propargylation of non‐enolizable norbornyl α‐diketones and an efficient AgI‐catalyzed cycloisomerization of the resulting α‐keto homopropargyl alcohols with terminal alkynes leading to spirocyclic dihydrofurans have been reported. The dihydrofurans obtained were subjected to hydrogenation to afford spiro tetrahydrofuran derivatives in nearly quantitative yields (98–99 %). Eventually, the prepared α‐spiro tetrahydrofuran norbornyl monoketones were utilized as precursors for acid‐mediated Grob‐type fragmentation reactions and converted into 1‐oxaspiro[4.5]decan‐6‐one derivatives by treatment with p‐toluenesulfonic acid.

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Lead(iv) acetate: intriguing reactivity profile

Cited by 7 publications

References 27 publications

Lead(IV) Acetate

Lead(IV) Acetate

ChemInform Abstract: Lead(IV) Acetate: Intriguing Reactivity Profile.

Diastereoselective Synthesis of Spirocyclic Dihydrofurans and 1‐Oxaspiro[4.5]decan‐6‐one Derivatives from Norbornyl α‐Diketones

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