Electrical resistivity and Hall effect measurements of pellets compacted from fullerene-like WS 2 nanoparticles (IF-WS 2 ) and bulk 2H-WS 2 powder were carried out using the van der Pauw method over a wide temperature range. In addition IF-WS 2 pellets were annealed at elevated temperatures under vacuum in a specially designed system. Arrhenius plots for the conductivities of the WS 2 samples (2H, IF and IF+annealing) exhibit marked uprise of ∂ ln (s T -1 )/∂T -1 with temperature. The resistivity of the nonannealed IF-WS 2 pellets is higher by 2 -8 orders of magnitude than that of 2H-WS 2 pellets, whereas the resistivity of the annealed IF pellets is higher than that of the non-annealed ones. Hall Effect measurements at 300 K show p-type conductivity and similar carrier concentration for both types of materials. The carrier mobility of 2H-WS 2 platelets is found to be in the range of the reported values. However, IF-WS 2 pellets have shown an unusually low mobility for a semiconducting material. The experimental data was found to be in a good agreement with a model used for analyzing the conductivity of polycrystalline semiconductors, which takes into consideration fluctuations of the barrier heights among the different nanoparticles as well as within a single nanoparticle boundary.