Layer-by-Layer Grafting of Molecularly Imprinted Polymers via Iniferter Modified Supports

Sellergren, Börje; Rückert, Bärbel; Hall, Andrew J.

doi:10.1002/1521-4095(20020903)14:17<1204::aid-adma1204>3.0.co;2-o

Cited by 112 publications

(65 citation statements)

References 1 publication

(2 reference statements)

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“…In this method, thin imprinted layers have been successfully used as coatings on chromatography-grade porous silica using several techniques to restrain the radical polymerization at the surface of the beads [81][82].…”

Section: Surface Imprinting Polymerizationmentioning

confidence: 99%

Characteristic and Synthetic Approach of Molecularly Imprinted Polymer

Yan

Row

2006

IJMS

436

231

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Abstract:Molecularly imprinted polymers (MIP) exhibiting high selectivity and affinity to the predetermined molecule (template) are now seeing a fast growing research. However, optimization of the imprinted products is difficult due to the fact that there are many variables to consider, some or all of which can potentially impact upon the chemical, morphological and molecular recognition properties of the imprinted materials. This review present a summary of the principal synthetic considerations pertaining to good practice in the polymerization aspects of molecular imprinting, and is primarily aimed at researcher familiar with molecular imprinting methods but with little or no prior experience in polymer synthesis. The synthesis, characteristic, effect of molecular recognition and different preparation methods of MIP in recent few years are discussed in this review, unsolved problems and possible developments of MIP were also been briefly discussed.

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Section: Surface Imprinting Polymerizationmentioning

confidence: 99%

Characteristic and Synthetic Approach of Molecularly Imprinted Polymer

Yan

Row

2006

IJMS

436

231

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“…In a series of papers, Sellergren described the development of MIP films by grafting methods. [102][103][104][105][106][107] His group used silica particles bearing surface-immobilized, free radical azo-initiator species to favor grafting polymerization on the particle's surface over polymer growth in solution. In his research, L-phenylalanine anilide was used as a template in the polymerization of MAA and EDMA functionalized monomers.…”

Section: Resolution Of Enantiomersmentioning

confidence: 99%

Biomimetic Polymers for Chiral Resolution and Antifreeze Applications

Medina¹,

Mastai²

2011

On Biomimetics

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“…This approach allowed homogeneous grafting on the pore walls of the support preventing agglomeration of particles. In addition, the living nature of the iniferter grafts may offer the possibility of consecutive grafting of multiple polymer layers with different molecular recognition features [33]. Although the composite particles obtained exhibited enantioselectivity in the chromatographic mode, further research should be done to demonstrate that this methodology might represent a general way to prepare MIP beads with improved chromatographic characteristics.…”

Section: Imprinting In Preformed Beadsmentioning

confidence: 99%

Molecularly imprinted polymers: towards highly selective stationary phases in liquid chromatography and capillary electrophoresis

Turiel

Martín‐Esteban

2004

Analytical and Bioanalytical Chemistry

149

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Molecularly imprinted polymers (MIPs) are synthetic polymers with a predetermined selectivity for a given analyte, or group of structurally related compounds, that make them ideal materials to be used in separation processes. In this sense, it is not surprising that the first applications of MIPs were as tailor-made chiral stationary phases in liquid chromatography. However, peak broadening and tailing, especially of the more retained enantiomers, were observed. Accordingly, this paper gives an overview of the attempts carried out during the recent years to improve the chromatographic performance of MIPs in liquid chromatography and capillary electrophoresis as well as the more recent applications. We conclude that MIPs are very promising materials to be used as selective stationary phases in chromatography although further developments are necessary in order to fully exploit their potential.

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Layer-by-Layer Grafting of Molecularly Imprinted Polymers via Iniferter Modified Supports

Cited by 112 publications

References 1 publication

Characteristic and Synthetic Approach of Molecularly Imprinted Polymer

Characteristic and Synthetic Approach of Molecularly Imprinted Polymer

Biomimetic Polymers for Chiral Resolution and Antifreeze Applications

Molecularly imprinted polymers: towards highly selective stationary phases in liquid chromatography and capillary electrophoresis

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