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Thermal expansion of materials is a topic of age-old interest to mankind in view of the chronological development of several devices and technologies [1,2]. The concept of thermal expansion and knowledge of thermal expansion coefficient of materials remain important for any structural materials experiencing a temperature gradient. The structural materials include any material used in technology to build a mechanically or electronically integrated physical entity. In particular, the thermal properties are of interest when any structural assembly faces a temperature variation. Thermal expansion effects have been well considered right from the metals and ceramic parts of cookwares to the highly sophisticated mechanical structures, such as buildings, bridges, air/spacecraft, vessels, kilns, furnaces, and so on. In particular, metals such as steel, copper, and so on that are important structural parts show a significant expansion with temperature. Thus, in all these materials, thermal expansion was exploited either to enhance or to nullify any temperature-induced dimensional instability, for example, the utilization of thermal expansion in automatic cut-off switch using bimetals is well known. The discovery of Invar (an alloy of 35% Ni and 65% Fe) and subsequent modified compositions as Elinvar, Kovar, Alnico, and so on have found immense applications in modern technologies, such as design of high-accuracy clocks, shadow mask in television screen, and so on [3]. In addition, low thermal expansion in fused silica and controllable thermal expansion in materials with glass and glass-ceramic compositions have been discovered and used in precise optical instruments, mirror substrates, glass-metal junctions [4,5]. A large number of crystalline materials with low thermal expansion are also discovered [6]. Thermal expansion data of ceramics have been a prime consideration in the designing of electrolyte and electrodes of solid oxide fuel cells [7]. Similarly, thermal expansion data of nuclear fuel materials are significant in preventing detrimental effects of fuel-clad interaction and unwanted swelling of fuel pins [8]. Nuclear reactor performance is mainly restricted by the thermal expansion and thermal conductivity of the fuel pellets under irradiation conditions. In these j197 applications, the material property is more significant than the structural assembly and hence the structural materials are tuned as per their thermal expansion behavior. However, the thermal expansion behavior of electronic materials causing temperature-induced dimensional instability leading to circuit failure also needs to be dealt with. Considering such aspects, several Invar-type alloys and metal matrix composites are developed in recent years [9]. Thus, the thermal expansion data of any material are the first requisite for the development of most of the technologies.In general, it is known that all materials expand or contract with the rise or fall of temperature. The thermal expansion of any material is explained as a relative change in dimens...
Thermal expansion of materials is a topic of age-old interest to mankind in view of the chronological development of several devices and technologies [1,2]. The concept of thermal expansion and knowledge of thermal expansion coefficient of materials remain important for any structural materials experiencing a temperature gradient. The structural materials include any material used in technology to build a mechanically or electronically integrated physical entity. In particular, the thermal properties are of interest when any structural assembly faces a temperature variation. Thermal expansion effects have been well considered right from the metals and ceramic parts of cookwares to the highly sophisticated mechanical structures, such as buildings, bridges, air/spacecraft, vessels, kilns, furnaces, and so on. In particular, metals such as steel, copper, and so on that are important structural parts show a significant expansion with temperature. Thus, in all these materials, thermal expansion was exploited either to enhance or to nullify any temperature-induced dimensional instability, for example, the utilization of thermal expansion in automatic cut-off switch using bimetals is well known. The discovery of Invar (an alloy of 35% Ni and 65% Fe) and subsequent modified compositions as Elinvar, Kovar, Alnico, and so on have found immense applications in modern technologies, such as design of high-accuracy clocks, shadow mask in television screen, and so on [3]. In addition, low thermal expansion in fused silica and controllable thermal expansion in materials with glass and glass-ceramic compositions have been discovered and used in precise optical instruments, mirror substrates, glass-metal junctions [4,5]. A large number of crystalline materials with low thermal expansion are also discovered [6]. Thermal expansion data of ceramics have been a prime consideration in the designing of electrolyte and electrodes of solid oxide fuel cells [7]. Similarly, thermal expansion data of nuclear fuel materials are significant in preventing detrimental effects of fuel-clad interaction and unwanted swelling of fuel pins [8]. Nuclear reactor performance is mainly restricted by the thermal expansion and thermal conductivity of the fuel pellets under irradiation conditions. In these j197 applications, the material property is more significant than the structural assembly and hence the structural materials are tuned as per their thermal expansion behavior. However, the thermal expansion behavior of electronic materials causing temperature-induced dimensional instability leading to circuit failure also needs to be dealt with. Considering such aspects, several Invar-type alloys and metal matrix composites are developed in recent years [9]. Thus, the thermal expansion data of any material are the first requisite for the development of most of the technologies.In general, it is known that all materials expand or contract with the rise or fall of temperature. The thermal expansion of any material is explained as a relative change in dimens...
The electronic and thermodynamic complexity of plutonium has resisted a fundamental understanding for this important elemental metal. A critical test of any theory is the unusual softening of the bulk modulus with increasing temperature, a result that is counterintuitive because no or very little change in the atomic volume is observed upon heating. This unexpected behavior has in the past been attributed to competing but never-observed electronic states with different bonding properties similar to the scenario with magnetic states in Invar alloys. Using the recent observation of plutonium dynamic magnetism, we construct a theory for plutonium that agrees with relevant measurements by using density-functional-theory (DFT) calculations with no free parameters to compute the effect of longitudinal spin fluctuations on the temperature dependence of the bulk moduli in δ-Pu. We show that the softening with temperature can be understood in terms of a continuous distribution of thermally activated spin fluctuations.T he plutonium δ-phase (face-centered cubic, fcc), depending on gallium concentration, can on heating expand (above ∼2 at % Ga), contract (less than ∼2 at % Ga), or maintain volume independent of temperature from approximately 500 to 800 K (∼2 at % Ga) (1). Reminiscent of the Invar effect (2, 3), Lawson et al. (1) made the critically important observation that this could be modeled by assuming that two configurations were thermodynamically accessible in δ-Pu. This assumption introduces a strong constraint on a microscopic theory. Separated by 1,400 K, the higher energy configuration is assumed to have smaller volume than the lower energy one. Thus, as temperature rises, the Boltzmann factor increases the occupied fraction of the higher energy state, compensating for ordinary thermal expansion effects. This model could be made to fit δ-Pu's volume versus temperature dependence as measured by elastic neutron scattering for the range of Ga concentrations typically used to stabilize the δ-phase (4). However, measurements of the elastic moduli of polycrystalline Pu-Ga alloys by Suzuki et al. (5) showed that the bulk modulus softened substantially on warming in temperature regions where the atomic volume remained fixed. In an attempt to include elastic softening as temperature increased and volume decreased, Lawson et al.(1) made the unusual conjecture that the higher energy state with smaller volume, required to get the thermal expansion correct, must make no contribution to the bulk modulus. The usual situation is that a higher energy state with lower volume is stiffer, not softer as required here. Although the multiple-configuration assumption is now strongly supported by recent measurements (6), the yet-unexplained anomalous behavior (softening on warming with no volume change) remains a critical missing component of a fundamental understanding of δ-Pu.The detailed issue then is that the bulk and shear moduli of δ-Pu soften with temperature at a rate an order of magnitude greater than other metals with similar...
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