2023
DOI: 10.1021/jacs.3c11742
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Late-Stage Chemo- and Enantioselective Oxidation of Indoles to C3-Monosubstituted Oxindoles

Song Li,
Xigong Liu,
Chen-Ho Tung
et al.
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Cited by 5 publications
(2 citation statements)
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“…The combination of salen and group 4 transition-metals have enabled various exceptional asymmetric oxidations, , where structural characterizations of catalysts facilitated the mechanism elucidations. Since the Hf-salen complex was able to achieve outstanding reactivity in epoxidation, its catalysis model was worth studying.…”
Section: Results and Discussionmentioning
confidence: 99%
“…The combination of salen and group 4 transition-metals have enabled various exceptional asymmetric oxidations, , where structural characterizations of catalysts facilitated the mechanism elucidations. Since the Hf-salen complex was able to achieve outstanding reactivity in epoxidation, its catalysis model was worth studying.…”
Section: Results and Discussionmentioning
confidence: 99%
“…In this section we briefly discuss the magnesium catalytic method for the asymmetric synthesis of indole- or oxindole-related structures (Scheme 19). 54 Pyrroloindolines bearing a C3 quaternary stereocenter are common and important building blocks and serve as a typical subclass of indole alkaloids. In 2015, our group achieved a direct synthetic strategy for rapid construction of pyrroloindolines by using C3-substituted indole and meso -aziridine as easily accessed feedstocks.…”
Section: The Enantioselective Synthesis Of Indole- or Oxindole-relate...mentioning
confidence: 99%