a b s t r a c tThe Upper Frasnian sequence of the Namur-Dinant Basin in southern Belgium consists of mixed siliclasticcarbonate succession of a ramp setting, where the sequence spans the rhenana-linguiformis conodont zones. Earlier studies investigated the chemostratigraphic variations during the Frasnian-Famennian event, but little has been yet known about the nature of the counterpart variations that immediately preceded that time interval. Despite the scarcity of well-preserved brachiopods, sixty-one calcitic shells were collected mainly from beds of the Neuville and Les Valisettes formations (Lower and Upper rhenana zones), to investigate biochemostratigraphic profiles of oxygen-, carbon-isotope and rare earth element (REE) variations of 18 13 Upper Frasnian Namur-Dinant Basin Belgium the time interval immediately before the Frasnian-Famennian boundary. The δ O and δ C values of the well-preserved shells range from − 9.5 to − 5.6‰ VPDB (− 7.7 ± 1.1, n = 33) and from − 1.8 to 3.8‰ VPDB (1.1 ± 1.7, n = 33), respectively, which are within the documented global values. The C-and O-isotope profiles exhibit parallel shifts, particularly at the top of the Neuville Formation (top of the Lower rhenana Zone), which are associated with a sea-level rise and shrinkage in the brachiopod community. Also, the Th/U (0.9 ± 0.6, n = 16) and Ce/Ce* (2.2 ± 0.5, n = 16) ratios suggest deposition under reducing conditions consistent with sea transgression.