Conspectus
Laser diodes (LDs), free of
“efficiency droop”, can
bear a superhigh power density. Laser-driven white light sources (blue
LD + laser phosphors), which promise super brightness and high directionality,
have emerged for various applications, including lighting, displays,
communications, and endoscopy. Laser phosphors are critical components
of this technology, which determine the luminous efficacy, luminance,
and color quality of the device. However, most phosphors suffer from
serious luminance saturation when excited by a high-power-density
blue laser. The synergetic effect of thermal quenching and photoexcitation
quenching causes the luminance saturation, named thermally and optically
induced luminance saturation, respectively. To avoid luminance saturation,
laser phosphors should have the following merits to withstand a high-power-density
laser excitation: (i) high internal quantum efficiency; (ii) small
Stokes shift; (iii) low thermal quenching; (iv) high thermal conductivity;
(v) short decay time. Robust inorganic phosphor bulks have been developed
for laser excitation. Among them, phosphor ceramics are the best choice
for high-power-density laser excitation owing to their excellent reliability
and rich microstructure tunability, and phosphor films act as a complementary
component to realize flexible color tuning with low fabrication cost.
Moreover, property evaluation methods for LED phosphors are not all
suitable for laser phosphors, as the light conversion process occurs
only within a small light spot area. First, the color-conversion process
in laser-driven lighting occurs at a small interface between the excitation
blue laser and the phosphor, and the output luminous flux is collected
from either the transmissive or the reflective side for practical
applications. Therefore, when evaluating the luminous flux of a laser
phosphor, the sample should be placed at the entrance or exit of the
integrating sphere rather than in the center of the integrating sphere
as in LED lighting. Second, the incident blue laser spot tends to
broaden during the color-conversion process. Comparison of the incident
laser spot with the real light spot provides a descriptor to evaluate
the light confinement ability of the laser phosphor. The real light
spot area is also a key parameter for calculating the luminance of
the light source. Therefore, the precise measurement of the light
spot area is very important, but most researches have ignored it.
Third, the excitation blue light is highly collimated with a Gaussian-distributed
energy, whereas the phosphor-converted yellow light energy follows
a Lambertian distribution. This intrinsic difference leads to uneven
mixing of blue and yellow light, and the light uniformity of laser-driven
white light sources must be measured to evaluate the color quality.
Furthermore, this account also proposes future research priorities
of discovering high-performance red-emitting laser phosphors and extending
the applications to communications. This Account will promote scientific
and tech...