“…In the last decade, several attempts were carried out to reveal the metallurgical phenomena that take place during reactive surface treatment of pure iron Illgner et al, 1995Illgner et al, , 1996Landry et al, 1999; with a pulsed excimer laser. Depending on the operational laser parameters (energy density, frequency, number of pulses and laser intensity distribution), nitrogen distribution reached a depth of about 300 nm, while the nitrogen content from 22 at.% at the surface was found to decrease to 4 at.% and the main phases identified within the treated zone were ␥-Fe(N), coexisting (␥ + ) and finally pure -Fe x N. Similar results were obtained in more recent studies on the excimer laser nitriding of steels (Schaaf et al, 1998 , the main difference being the formation of carbonitrides due to the presence of carbon.…”