While optical diagnostic techniques have been applied with great success to the fundamental study of combustion chemistry and physics in the laboratory, the challenges afforded by real-world propulsion systems demand continuing innovation if such techniques are to be adapted and transitioned for use in engineering test and on-board monitoring and control applications. A desire to achieve measurement tools in new spectral territory that exploit limited available optical access and provide high data-acquisition bandwidth has motivated the development efforts described in this paper. An ultranarrowband, mid-infrared optical parametric oscillator, terahertz transmitters and receivers for studies in the far-infrared, and high-speed imaging systems based on modelocked lasers and high-framingrate cameras represent just a few of the potential solutions now under development for current and future combustion and propulsion applications.