Large-scale synthesis, mechanism, and application of a luminescent copper hydride nanocluster

Abstract

Photoluminescence mechanism and selective sensing of Ag+ by Cu4H nanoclusters synthesized at a large scale.

Hydride-doped coinage metal superatoms and their catalytic applications

“…In the 1 H NMR spectrum, the hydride resonances within the NCs demonstrate a broad chemical shift range spanning from −16 to +16 ppm, 20,21,32,63–67 as summarized in Table 1. Specifically, for homometallic copper NCs, these resonances are observed between −2 and 9 ppm.…”