Switchable‐hydrophilicity solvents (SHSs) are solvents that can switch reversibly between a water‐miscible state to a state that forms a biphasic mixture with water. In this case study, SHSs have been studied for easy product/catalyst separation as well as catalyst recycling. A series of tertiary amine SHSs have been identified for the extraction of the hydrophilic product from the postreaction mixture. Here, we determined high extraction efficiencies for the product (>84 %) and low extraction rates for the catalyst (<0.1 %). With the catalyst recycling experiments, we isolated the product in high purity (>98 %) without further purification steps. At the same time, the catalyst was reused without any loss of activity (>91 % enantiomeric excess, >99 % yield) four times. Furthermore, we optimized the extraction efficiency by working with a microextractor. In addition, with the use of a falling‐film microreactor, we obtained the product with high enantioselectivity by working at ambient conditions.