Lanthanum(III) chlorite trihydrate, La(ClO2)3.3H2O: a redetermination

Bisi, C. Castellani

doi:10.1107/s0108270184007022

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Anhydrous Ternary Nitrates1

Bent and Linear Anions1

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2002

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“…For the nitrates with the highest A + content, A 6 M(NO 3 ) 9 , two structure types are known. According to the formulation A 6 [M(NO 3 ) 6 ](NO 3 ) 3 both the monoclinic (NH 4 ) 6 Nd(NO 3 ) 9 (Figure b) and the trigonal-rhombohedral silver nitrates Ag 6 M(NO 3 ) 9 (M = Ce, Pr) , (Figure a) contain the hexanitrate complexes [M(NO 3 ) 6 ] 3- and additional free nitrate ions. Again, the different structures arise from the different A + sizes.…”

Section: Anhydrous Ternary Nitratesmentioning

confidence: 99%

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Inorganic Lanthanide Compounds with Complex Anions

2002

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Mathias S. Wickleder was born in Bergen, Germany, in 1965. He received his Dr. rer. nat. degree at the University of Hannover under the direction of Professor G. Meyer in 1994. Thereafter he joined the group of Professor H. U. Gu ¨del, Bern, Switzerland, as a postdoctoral fellow for two years. In 2000 he finished his Habilitation at the Institute for Inorganic Chemistry in Cologne. His research interests include the structural chemistry and thermal behavior of rare-earth and transition-metal compounds with complex anions.

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Section: Anhydrous Ternary Nitratesmentioning

confidence: 99%

“…Chlorites of composition M(ClO 2 ) 3 · x H 2 O with x varying between 0.5 and 4 were prepared roughly 40 years ago in a metathesis reaction of the nitrates M(NO 3 ) 3 and sodium chlorite NaClO 2 . Unfortunately, only one of these chlorites, La(ClO 2 ) 3 ·3H 2 O, has been structurally investigated .…”

Section: Bent and Linear Anionsmentioning

confidence: 99%