Lanthanidomesogens

Metallomesogens: Retrospectives and Perspectives

“…Кроме того, вышло много обзоров по отдельным направлениям в области металломезогенов, например лантанидомезогенов [15][16][17], золото-содержащих жидких кристаллов [18,19], ферро-ценомезогенов [20][21][22], ионных металломезогенов [23,24], полимерных металломезогенов [25,26], лиотропных металломезогенов [27], неоргани-ческих или металлоколлоидных жидких крис-таллов [28][29][30] и жидкокристаллических металло-дендримеров [31]. Куном Биннемансом представ-лена специальная глава к книге о молекулярных материалах, посвященная физическим свойствам металломезогенов [32].…”

Grand challenges in inorganic chemistry: toward better life quality and a more sustainable world

“…Inorganic molecular systems with specific structures are the core of many functional materials, especially when electronic or lighting devices are concerned. Metallomesogens which combine the properties of metals (luminescence, magnetism) with those of liquid crystals (fluidity, anisotropy, response to electric fields) belong to a class of compounds which may yield interesting features, particularly with respect to magnetic switching and magneto-optical data storage (Binnemans, 2013 ). Another fascinating development is the design of single molecule magnets (SMMs) the properties of which can be modulated thanks to weak interactions in multidimensional supramolecular arrangements, e.g., through hydrogen bonds.…”

Thermal and Emission Properties of a Series of Lanthanides Complexes with N-Biphenyl-Alkylated-4-Pyridone Ligands: Crystal Structure of a Terbium Complex with N-Benzyl-4-Pyridone

“…Liquid crystals based on lanthanide complexes (lanthanidomesogens) are well-investigated anisotropic materials that develop interesting photophysical properties [ 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 ]. Along the time, the unique photophysical properties of the lanthanide ions provided a strong fundament for the design and study of their complexes with liquid crystal properties and these compounds are mainly built around several categories of organic ligands, among the most used were the Schiff bases, β-diketonates, alkanoates, different macrocyclic ligands (phthalocyanine, porphyrin, etc.…”