Lanthanide metal-organic frameworks for luminescent sensing and light-emitting applications

Advances of Metal-Organic Frameworks in Adsorption and Separation Applications

“…Reprinted with permission from ref [11]. 除上文提到的几类 MOFs 之外, 较经典的 MOFs 材 料还有 HKUST-1 [13] 、Bio-MOF 系列 [14] 、PCN 系列 [15] 和 CPO [16] [17] , 碳捕获 [18] , 废水处理 [19] , 燃油净化 [20] , 萃取 吸附剂 [21] , 色谱固定相 [6] 等 催化反应 氢化反应, 光催化反应、烃类, 醇类氧化反应、醇类氧化反应、 酯化反应、水解反应 [22] 等 传感 电化学传感器 [23] 、荧光化学传感器 [24,25] 等 生物医学 药物负载 [26] 、药物缓释 [27] 等 电学 电池、超级电容器 [28] 等 目前, 针对 MOFs 材料的研究还多集中于实验室的 学术研究, 工业大规模的生产和应用案例还相对较少. 但由于 MOFs 材料作为多孔材料优良的性质和极大的应 用潜力, 近年来将其投入实际生产应用的实例越来越 多 .…”

A 12-Fold ThSi2 Interpenetrated Network Utilizing a Glycine-Based Pseudopeptidic Ligand

“…Ever since their popularization in the last decade, coordination polymers (CPs), also known as metal-organic frameworks (MOFs), have become one of the most prominent branches of inorganic and materials chemistry, in no small part due to the extensive variety of their applications [1][2][3][4][5][6][7][8]. A key factor for the rise of CPs as functional materials has been the development of rational synthetic routes towards the optimization of their application potential [9][10][11][12].…”

Luminescence and Magnetic Properties of Two Three-Dimensional Terbium and Dysprosium MOFs Based on Azobenzene-4,4′-Dicarboxylic Linker

“…Given that, classically, the first scientific efforts were focused on the use of MOF as possible porous materials for gas storage and separation, the study of their luminescent and magnetic properties have been forgotten. However, increasingly, researchers try to obtain multifunctional MOFs with new interesting physical properties that can give another perspective to MOF's applications, such as luminescence sensors due to metal-ligand charge transfer [14]. In recent years, we have designed and synthesized novel Lanthanide-MOFs with different nitrogen derivative ligands with interesting luminescent properties [15] and constructed single-molecule magnets (SMM) based on dysprosium, able to show interesting effective energy barriers [16,17].…”