Lanthanide-Catalyzed Synthesis of Cyclic Silicon-Containing Di- and Triperoxides

Makhmudiyarova, N. N.; Ishmukhametova, I. R.; Ибрагимов, А. Г.

doi:10.1134/s1070428020100024

Cited by 3 publications

(2 citation statements)

References 32 publications

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“…N. N. Makhmudiyarova et al were the first to synthesize eight- and 11-membered cyclic silicon-containing di- and triperoxides with high yields and selectivity by the reaction of geminal bis-hydroperoxides with bis(methoxymethyl)-diphenylsilane in the presence of La(NO 3 ) 3 ·6H 2 O as a catalyst ( Scheme 8 ) [ 42 ]. Eleven-membered diphenylhexaoxasiladispiro cycloalkanes were reduced to the corresponding diphenyltetraoxasiladispiroalkanes.…”

Section: Arylsilanes—the Most Commonly Used Synthesesmentioning

confidence: 99%

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Conducting Silicone-Based Polymers and Their Application

et al. 2021

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Over the past two decades, both fundamental and applied research in conducting polymers have grown rapidly. Conducting polymers (CPs) are unique due to their ease of synthesis, environmental stability, and simple doping/dedoping chemistry. Electrically conductive silicone polymers are the current state-of-the-art for, e.g., optoelectronic materials. The combination of inorganic elements and organic polymers leads to a highly electrically conductive composite with improved thermal stability. Silicone-based materials have a set of extremely interesting properties, i.e., very low surface energy, excellent gas and moisture permeability, good heat stability, low-temperature flexibility, and biocompatibility. The most effective parameters constructing the physical properties of CPs are conjugation length, degree of crystallinity, and intra- and inter-chain interactions. Conducting polymers, owing to their ease of synthesis, remarkable environmental stability, and high conductivity in the doped form, have remained thoroughly studied due to their varied applications in fields like biological activity, drug release systems, rechargeable batteries, and sensors. For this reason, this review provides an overview of organosilicon polymers that have been reported over the past two decades.

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Section: Arylsilanes—the Most Commonly Used Synthesesmentioning

confidence: 99%

“… Synthesis of di(tri)peroxysilacycloalkanes by cyclization and reduction of 11-membered diphenylhexaoxasiladispirocycloalkanes [ 42 ]. …”

Section: Figures Schemes and Tablesmentioning

confidence: 99%

Conducting Silicone-Based Polymers and Their Application

et al. 2021

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Synthesis of cyclic aza-peroxides (microreview)

Belyakova

Radulov

2021

Chem Heterocycl Comp

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Multicomponent Assembly of Bicyclic Aza-peroxides Catalyzed by Samarium Complexes and Their Cytotoxic Activity

Makhmudiyarova,

Ishmukhametova,

Tyumkina

et al. 2023

J. Org. Chem.

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An original strategy toward bridged tetraoxazaspirobicycloalkanes was developed. The synthesis is based on a three-component condensation–cyclization reaction of primary arylamines with 1,1′-peroxybis (1-hydroperoxycycloalkanes) and pentane-1,5-dial catalyzed by Sm(NO3)3·6H2O. The structures and conformations of the products were determined by X-ray diffraction analysis and 1H and 13C NMR spectroscopy. High cytotoxic activity and biological potential toward ferroptosis induction were found for the synthesized bicyclic aza-peroxides.

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Lanthanide-Catalyzed Synthesis of Cyclic Silicon-Containing Di- and Triperoxides

Cited by 3 publications

References 32 publications

Conducting Silicone-Based Polymers and Their Application

Conducting Silicone-Based Polymers and Their Application

Synthesis of cyclic aza-peroxides (microreview)

Multicomponent Assembly of Bicyclic Aza-peroxides Catalyzed by Samarium Complexes and Their Cytotoxic Activity

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