Multifunctional materials are needed for multidimensional
stimuli-sensing
devices to monitor equipment in complicated working situations. Energy
upconverting (UC) nanophosphors doped with rare earth ions are widely
studied as materials for optical temperature and pressure sensors
working via the control of fluorescence (luminescence) intensity ratio.
Nonetheless, most Er3+-doped materials still have limited
sensitivity of optical detection. In the present study, we attempted
to develop high-sensitivity Er3+-doped sensor nanophosphors
based on thermally coupled energy levelsTCLs (Stark components)
for temperature and pressure sensing purposes. On the basis of different
pairs of TCLs, especially those from the Stark sublevels of 2H11/2 and 4S3/2, the multiple temperature
and pressure sensing performances were evaluated. The sensitivities
of the pressure and temperature detection modes that are calculated
using the selected Stark sublevels are noticeably greater than those
based on the traditional TCLs (based on the whole bands). The findings
of our study demonstrate a pioneering method for the creation of optically
active, multifunctional materials and their integration into optoelectronic
devices, specifically for the purpose of serving as remote sensors
for low-pressure (vacuum) and -temperature measurements.