The electronic structure of the RCo x Ge 2 (R=Ce, Pr, Gd) compounds with the orthorhombic crystal structure of CeNiSi 2 -type was studied by X-ray photoemission spectroscopy. The valence bands of CeCo 0.86 Ge 2 and PrCo 0.85 Ge 2 compounds have the similar character. Near the Fermi level the broad peak corresponding to the Co 3d and R 4f and 5d6s states is observed. In the case of GdCo 0.64 Ge 2 , the strong intensity peak at 8.7 eV corresponding to Gd 4f states is observed. The analysis of the XPS spectra of Ce and Pr 3d 5/2 and 3d 3/2 in the Gunnarson-Schönhammer model give the information on the hybridization of the f orbital with the conduction band. The hybridization energy equal 93 eV for R=Ce and 143 eV for R=Pr, respectively indicate stability of the shell in these compounds.