“…Chromate conversion coatings also lead to a decrease in the FFC growth rates but increased severity of the attack is observed in the fi lament tail. [49][50][51] A decrease in rate has been related to the adhesion of the coating as a result of these surface pretreatments. [49][50][51] However, the effects of pretreatment that specifi cally alter surface Cu content in the form of IMC and replated Cu that drive cathodic electron transfer reactions (ETR) have not been investigated.…”
Section: Performing Organization Name(s) and Address(es)mentioning
“…Chromate conversion coatings also lead to a decrease in the FFC growth rates but increased severity of the attack is observed in the fi lament tail. [49][50][51] A decrease in rate has been related to the adhesion of the coating as a result of these surface pretreatments. [49][50][51] However, the effects of pretreatment that specifi cally alter surface Cu content in the form of IMC and replated Cu that drive cathodic electron transfer reactions (ETR) have not been investigated.…”
Section: Performing Organization Name(s) and Address(es)mentioning
“…The potential difference between the head and the tail can be up to 0.4 V, and this differential is the driving force for filiform corrosion [1]. The copper containing alloys of the 2xxx and 7xxx series are the most susceptible to filiform corrosion [5].…”
Section: Introductionmentioning
confidence: 99%
“…The corrosion protection system is generally made up of multiple components and incorporates a surface treatment, such as a chromate conversion coating, which can promote adherence of a paint layer [6] as well as imparting corrosion protection to the underlying metal [5,7]. An organic primer coating containing inhibitive pigments is applied to the chromate layer, with the inhibitor designed to leach out of the organic layer when corrosion activity occurs [8].…”
Mixed rare earth organophosphates have been investigated as potential corrosion inhibitors for AA2024-T3 with the aim of replacing chromate-based technologies. Cerium diphenyl phosphate (Ce(dpp) 3 ) and mischmetal diphenyl phosphate (Mm(dpp) 3 ) were added to epoxy coatings applied to AA2024-T3 panels and they were effective in reducing the amount and rate of filiform corrosion in high humidity conditions. Ce(dpp) 3 was the most effective and characterisation of the coating formulations showed approximately a factor of 5 reduction in both the number of corrosion filaments initiated as well as the length of these. Mm(dpp) 3 appeared to reduce the corrosion growth rate by a factor of 2 although it was the more effective inhibitor in solution studies. Spectroscopic characterisation of the coatings indicated that the cerium based inhibitor may disrupt network formation in the epoxy thus resulting in a coating that absorbed more water and allowed greater solubilisation of the corrosion inhibiting compound.
“…Standard practises used for the evaluation of corrosion performance include neutral salt-spray testing and filiform corrosion. In addition, a number of electrochemical techniques can be used to determine the degree or rate of corrosion of anodised aluminium 77,[111][112][113][114] , results from linear polarisation studies are presented, herein.…”
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