Kinetics Study of the Peroxidation of tert-Butyl Alcohol to tert-Butyl Hydrogen Peroxide in a Microreactor
Hongwei Zhu,
Junjie Yan,
Zhichen Zhang
et al.
Abstract:tert-Butyl hydroperoxide (TBHP), an organic peroxide, is mainly used as a polymer initiator and is typically synthesized by the thermal reaction of tert-butyl alcohol (TBA) with hydrogen peroxide (H 2 O 2 ). In this study, we adopted sulfuric acid (H 2 SO 4 ) as the homogeneous catalyst to promote the peroxidation reaction of TBA in a microchannel reactor. The reaction conditions for the synthesis of TBHP were optimized, and the kinetic model of the synthesis was subsequently established. The results show that… Show more
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