Kinetics of thallium(III)[and mercury(II)]-catalysed aquations of the chloropenta-amminecobalt(III) and cis- and trans-dichlorobis(ethylenediamine)cobalt(III) complexes

Foong, Siew‐Wan; Kipling, B.; Sykes, A. G.

doi:10.1039/j19710000118

Cited by 15 publications

(1 citation statement)

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“…In the Hg2+-catalyzed hydrolysis of Co(NH3)s-Cl2+, it was found that addition of chloride ions caused a rate increase of about 8% and this was attributed to HgCl+ catalysis. 32 Similarly, an 11% increase was observed in the Cr(NH3)sCl2+ system.33 Thus, the rate expression for these reactions should probably be written as -d[complex]/df = kaq[complex] + J/ngcV* [HgCl* 2"*][complex] (9…”

Section: Table VI Isosbestic Pointsmentioning

confidence: 99%

Acidopentaaminecobalt(III) complexes with polyamine ligands. VIII. Kinetics of hydrolysis of .pi.-, .KAPPA.-, and .omega.-chloro(ethylenediamine)(diethylenetriamine)cobalt(III) and .alpha.- and .beta.-chloro(ethylenediamine)(dipropylenetriamine)cobalt(III) cations in aqueous acidic solution

Huan¹,

Mulvihill²,

Gainsford³

et al. 1973

Inorg. Chem.

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Acidopentaaminecobalt(III) Complexessquare-planar arrangement is more suitable than an octahedral arrangement for bonding,, then the contrasting behavior of octahedral systems and square-planar systems can be understood. Evidence in the form of MO calculations,11 spectroscopic studies,11'12 and the results presented here support point (1) above; the second and third points are well established.22 There does not seem to be a need for two theories (symbiosis and MO) to account for the contrasting behavior discussed above. It seems unlikely that any theory (22) L. D.

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Section: Table VI Isosbestic Pointsmentioning

confidence: 99%

Acidopentaaminecobalt(III) complexes with polyamine ligands. VIII. Kinetics of hydrolysis of .pi.-, .KAPPA.-, and .omega.-chloro(ethylenediamine)(diethylenetriamine)cobalt(III) and .alpha.- and .beta.-chloro(ethylenediamine)(dipropylenetriamine)cobalt(III) cations in aqueous acidic solution

Huan¹,

Mulvihill²,

Gainsford³

et al. 1973

Inorg. Chem.

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ChemInform Abstract: KINETIK DER THALLIUM(III) UND (QUECKSILBER(II))‐KATALYSIERTEN AQUOTISIERUNG DER CHLOROPENTAMMINKOBALT(III)‐ UND CIS‐ UND TRANS‐DICHLORO‐BIS‐(AETHYLENDIAMIN)‐KOBALT(III)‐KOMPLEXE

Foong¹,

Kipling²,

Sykes³

1971

Chemischer Informationsdienst. Organische Chemie

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Kinetics and mechanism of electron transfer reactions. Reduction of mercury(II) chloride by L-ascorbic acid in acid perchlorate and chloride media

Agrawal

Mishra

Sharma

1992

Transition Met. Chem.

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Kinetics of thallium(III)[and mercury(II)]-catalysed aquations of the chloropenta-amminecobalt(III) and cis- and trans-dichlorobis(ethylenediamine)cobalt(III) complexes

Abstract: Kinetics of Thallium(1ii) [and Mercury(ii)]-catalysed Aquations of t h e Chloropenta-amminecobalt(ii1) and cis-and trans-Dichlorobis(ethy1enediamine)cobalt(iii) Complexes

Cited by 15 publications

References 0 publications

Acidopentaaminecobalt(III) complexes with polyamine ligands. VIII. Kinetics of hydrolysis of .pi.-, .KAPPA.-, and .omega.-chloro(ethylenediamine)(diethylenetriamine)cobalt(III) and .alpha.- and .beta.-chloro(ethylenediamine)(dipropylenetriamine)cobalt(III) cations in aqueous acidic solution

Acidopentaaminecobalt(III) complexes with polyamine ligands. VIII. Kinetics of hydrolysis of .pi.-, .KAPPA.-, and .omega.-chloro(ethylenediamine)(diethylenetriamine)cobalt(III) and .alpha.- and .beta.-chloro(ethylenediamine)(dipropylenetriamine)cobalt(III) cations in aqueous acidic solution

ChemInform Abstract: KINETIK DER THALLIUM(III) UND (QUECKSILBER(II))‐KATALYSIERTEN AQUOTISIERUNG DER CHLOROPENTAMMINKOBALT(III)‐ UND CIS‐ UND TRANS‐DICHLORO‐BIS‐(AETHYLENDIAMIN)‐KOBALT(III)‐KOMPLEXE

Kinetics and mechanism of electron transfer reactions. Reduction of mercury(II) chloride by L-ascorbic acid in acid perchlorate and chloride media

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