1945
DOI: 10.1021/ie50428a028
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Kinetics of Sucrose Crystallization.

Abstract: The third run was made under the same conditions using 1% concentrated sulfuric acid as catalyst. The temperature ranged from 135-132°C. during the 3-hour run, and the final percentage of esterification was 92.9. The three final products were very light in color. In all cases there was an initial drop in temperature after the acid and alcohol had reacted.

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Cited by 24 publications
(12 citation statements)
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References 6 publications
(11 reference statements)
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“…As usual, the lower growth rate along the second dimension leads to a higher degree of uncertainty due to the higher influence of the measurement error. On the basis of the obtained results, the first order of the sucrose crystal growth rate reported by many authors [6,7] was confirmed.…”
Section: Effect Of Supersaturationsupporting
confidence: 79%
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“…As usual, the lower growth rate along the second dimension leads to a higher degree of uncertainty due to the higher influence of the measurement error. On the basis of the obtained results, the first order of the sucrose crystal growth rate reported by many authors [6,7] was confirmed.…”
Section: Effect Of Supersaturationsupporting
confidence: 79%
“…Crystallization of sucrose has been widely investigated and many references on its crystallization kinetics can be found in the literature [5][6][7][8][9][10]. Among them, many works have focused on the determination of the growth kinetic parameters [6,7].…”
Section: Introductionmentioning
confidence: 99%
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“…Raw sugar and ethanol are the main products of the industrial process. Both sucrose and reducing sugars are the raw materials for ethanol, while reducing sugars inhibit the crystallization of sucrose . This means that increased amounts of reducing sugars result in increased ethanol yield instead of decreased sugar yield.…”
Section: Methodsmentioning
confidence: 99%
“…Others have studied the reduction of the crystal growth rate and the change in the crystal habit in the presence of impurities commonly found in the industrial process (Martins et al, 2005;Ouiazzane et al, 2008a;Van Hook, 1948, 1946. Van Hook (1945) performed experiments that suggested that, under certain operating conditions, the crystal growth rate is controlled by the step involving molecule deposition into the crystal lattice, rather than by the transport of sucrose across the crystal-solution boundary. Liang and Hartel (1991) proposed a model for crystal growth in a continuous crystallizer that considered the growth rate dispersion (the occurrence of different growth rates among the crystals) due to random fluctuations during the process.…”
Section: Introductionmentioning
confidence: 99%