Journal of Organometallic Chemistry

1975

DOI: 10.1016/s0022-328x(00)80698-1

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Kinetics of solvolysis reactions of pentaarylantimony compounds in 2-octanol

¹

,

Ronald J. Wikholm

²

,

³

et al.

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Cited by 12 publications

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ChemInform Abstract: KINETICS OF SOLVOLYSIS REACTIONS OF PENTAARYLANTIMONY COMPOUNDS IN 2‐OCTANOL

Lin³

et al. 1975

Chemischer Informationsdienst

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Aus Tetraphenylantimonfluorid (I) werden durch Umsetzung mit den Phenylmagnesiumbromiden (II) bei ‐20 bis 0°C die Pentaarylantimonverbindungen (III) hergestellt.

ChemInform Abstract: KINETICS OF SOLVOLYSIS REACTIONS OF PENTAARYLANTIMONY COMPOUNDS IN 2‐OCTANOL

Lin³

et al. 1975

Chemischer Informationsdienst

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Aus Tetraphenylantimonfluorid (I) werden durch Umsetzung mit den Phenylmagnesiumbromiden (II) bei ‐20 bis 0°C die Pentaarylantimonverbindungen (III) hergestellt.

Contrasting chemical and physical properties of [o‐ and [p‐(N,N‐dimethylamino) phenyl]phosphines and phosphonium salts

¹

,

²

1990

Heteroatom Chemistry

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The rate of' alkylutioii of' (2-N,N-diniethvlaniinophenvl)dipl?eiivlphospCii,ie with benzvl broinide in chlorofiwnz is faster than that of' the corresponding reuction of' (4-N ,N-diinethyluni inophenyl )diphenylphosphine. This result is disctissed in ternis o f u through-spucc N2,-P( IV) interaction for the fornier.The rule o/'ulkaliiie cleavage ofbe~izyl(4-N,N-diniethylaiiriiiophenvl)diphenylphosphoniuiii bromide, which gives toluene, is slower than the rate ofalkaline cleavage o/' l~eiizvl(2-N,N-diiiiethyluiiiinophenvl)diphenvlphosphoizitirii broniide, which gives dirnethvlaniline. This result is also discussed in ternis of' the t h rough-spuce N2 p-P( I V ) in teraction.The I'P N M R spectra of'a series ofortho-diineth-?iluinino-.suhstitirred triarylphosphines and benzyltriarylphosphoniunz halides show that the phosphorus utom is i m m shielded than in the corresponding para-diiiictlivlai~ii~io conipounds, as anticipated on the basis of.ui1 NZ,,-P(IV) interaction for the foriner.

Reaction of pentaarylantimony with acid halide, aldehyde and ketone

³

et al. 1996

Journal of Organometallic Chemistry

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