The present concerns surface modification of low alloy CrMoV steel by following the route of plasma nitriding for the improvement of hardness. Plasma nitriding was performed at a low temperature of 450 o C. The maximum hardness at this lower temperature was found to be ~1270 Hv after nitriding. At 550 o C though the hardness improvement near the surface region was similar but the core hardness was reduced. XRD studies revealed various nitrides of iron (γ′ (Fe 4 N) and ε (Fe 2-3 N)) with the ε nitride as the dominant phase. SEM analyses revealed the surface microstructure with almost no white layer. EDS point analyses shown the signature of N on the surface layer. It has been concluded in this study that the hardness of 90CrMoV8 steel can be improved significantly even at a low temperature of 450 o C without any of risk of the loss of core hardness.