Kinetics of homopolymerization of fluorinated acrylates, 5. Influence of the spacer between the fluorinated chain and the ester group

Guyot, Bernard; Améduri, Bruno; Boutevin, Bernard; Melas, Michel; Viguier, Michel; Collet, André

doi:10.1002/(sici)1521-3935(19980901)199:9<1879::aid-macp1879>3.0.co;2-d

Cited by 33 publications

(15 citation statements)

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“…Polyperfluoroacrylates have found applications in various fields, such as the protection of wood, paper, stone, optical fibers, and textiles. Various investigations have assessed the kinetics of commercially available acrylates3 and other synthesized monomers 4. In addition, the radical copolymerization of these fluoroacrylates with morpholine ethyl methacrylate has also been studied 5.…”

Section: Introductionmentioning

confidence: 99%

“…Various investigations have assessed the kinetics of commercially available acrylates3 and other synthesized monomers 4. In addition, the radical copolymerization of these fluoroacrylates with morpholine ethyl methacrylate has also been studied 5. Coating applications have drawn our attention in previous articles,6, 7 in which we report the behavior of photocrosslinked films based on acrylic resins and containing different fluorinated esters of the following type: where R f is a perfluorinated alkyl group and G is a hydrogenated spacer.…”

Section: Introductionmentioning

confidence: 99%

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Effect of the structural parameters of a series of fluoromonoacrylates on the surface properties of cured films

Améduri

Bongiovanni

Lombardi

et al. 2001

J. Polym. Sci. A Polym. Chem.

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A series of fluorinated acrylates [F(CF 2 ) q O(CH 2 ) p OOCOCHACH 2 , where q ϭ 8 and p ϭ 2 Ϭ 11) were synthesized and used as comonomers in the photopolymerization of acrylic systems. These fluoroacrylates were synthesized in a three-step procedure through the radical addition of perfluoroalkyliodides to an unsaturated alcohol followed by their acrylation. The mixtures, containing up to 0.8% (w/w) of the comonomers, produced transparent films after UV curing; they showed changes in the surface properties as a function of the comonomer type and concentration. With contactangle and X-ray photoelectron spectroscopy analyses, the relationship between the structure of the monomers and the surface properties of the UV-cured films was investigated: the wettability decreased, depending on the length of the fluorinated group (q value) and the hydrogenated segment of the monomer (p value).

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Effect of the structural parameters of a series of fluoromonoacrylates on the surface properties of cured films

Améduri

Bongiovanni

Lombardi

et al. 2001

J. Polym. Sci. A Polym. Chem.

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“…and plotting the experimental values of ln([M] 0 /[M]) versus

(1 - e^{- \frac{k_{d} t}{2}})

enabled to assess the square of the propagation rate to the termination rate, k p 2 / k t , (Fig. ) from the slope of the straight line, considering the rate of decomposition of the initiator, k d (AIBN in acetonitrile at 80 °C) as 1.25 × · 10 −4 s −1 , whereas the efficiency of the initiator ( f ) was 0.6.…”

Section: Resultsmentioning

confidence: 99%

Conventional radical polymerization and iodine‐transfer polymerization of 4′‐nonafluorobutyl styrene: Surface and thermal characterizations of the resulting poly(fluorostyrene)s

Ceretta

Zaggia

Conte

et al. 2013

J. Polym. Sci. Part A: Polym. Chem.

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4 0 -Nonafluorobutylstyrene (3) was synthesized and polymerized by conventional and controlled radical polymerization (iodine transfer polymerization (ITP)). Such an aromatic fluoromonomer was prepared from Ullmann coupling between 1-iodoperfluorobutane and 4-bromoacetophenone followed by a reduction and a dehydration in 50% overall yield. Two radical polymerizations of (3) were initiated by AIBN either under conventional or controlled conditions, with 1-iodoperfluorohexane in 84% monomer conversion and in 50% yield. ITP of (3)

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“…As previously investigated through both theoretical and experimental approaches, polymerization kinetic parameters not only depend on temperature, pressure, and halogen (X), but also are influenced by ligand and initiator structure . Our present work focuses on the numerical investigation for estimating various ATRP equilibrium constants using different initiator types and catalytic complexes.…”

Section: Introductionmentioning

confidence: 99%

Insight into the ATRP rate controlling ability of initiator structure: Micromolecular, macromolecular, and immobilized initiators

Zhou

Luo

2014

J. Polym. Sci. Part A: Polym. Chem.

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The equilibrium constant (K ATRP ) is a key factor for ensuring a successful atom transfer radical polymerization (ATRP), which guarantees a controlled process with predictable product properties. In this work, the effect of initiator type (i.e., micromolecular, macromolecular, and immobilized initiator) on the ATRP kinetics was studied through a developed mathematical model. It was validated thoroughly via experiments using fluorinated monomer (2,2,3,3,4,4,4-heptafluorobutyl methacrylate) as model component. The results show that the activity and deactivity of the copper(I) chlorine/1,1,4,7,7-pentamethyldiethylenetriamine (Cu I Cl/PMDETA) heterogeneous catalytic complex is the highest for ethyl 2-bromoisobutyrate (Eib-Br), lower for bromo-poly(styrene) (PS-Br), and the lowest for bromo-aminopropyl functionalized SiO 2 (SiO 2 -APTS-Br). The initiation system of Eib-Br with Cu I Cl/4,4 0 -dinonyl-2,2 0 -bipyridyl (dNbpy) has relatively lower activating ability, but the polymerization keeps controllable by its higher deactivating ability. In addition, this homogeneous catalytic system (Cu I Cl/dNbpy) is facile for further implementing the developed model to guide for the preparation of fluorinated gradient copolymers by semi-batch ATRP.

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Kinetics of homopolymerization of fluorinated acrylates, 5. Influence of the spacer between the fluorinated chain and the ester group

Cited by 33 publications

References 0 publications

Effect of the structural parameters of a series of fluoromonoacrylates on the surface properties of cured films

Effect of the structural parameters of a series of fluoromonoacrylates on the surface properties of cured films

Conventional radical polymerization and iodine‐transfer polymerization of 4′‐nonafluorobutyl styrene: Surface and thermal characterizations of the resulting poly(fluorostyrene)s

Insight into the ATRP rate controlling ability of initiator structure: Micromolecular, macromolecular, and immobilized initiators

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