Kinetics of crack growth on polyisoprene vulcanizates in ozone atmosphere

Разумовский, С. Д.; Podmaster’ev, V. V.; Zaikov, G.Ye.

doi:10.1016/0032-3950(86)90099-7

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“…A plot of elution volumes of these GPC peaks against molecular weight was linear. Razumovskii et al (78) studied the kinetics of the decrease in stress (Dp) in isoprene rubber vulcanisates at 22° and in an ozone concentration of 1.8-7.3 x 10 -8 mol/L, and the kinetics of degradation of the rubber macromolecules in solution were studied. The number of ruptured macromolecules increased linearly with time, whereas the time dependence of Dp was more complex.…”

Section: Sequence Length Distributionmentioning

confidence: 99%