2007
DOI: 10.3176/oil.2007.1.04
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Kinetics of Co-Pyrolysis of Tarfaya (Morocco) Oil Shale With High-Density Polyethylene

Abstract: Pyrolysis kinetics of oil shale mixed with high-density polyethylene (HDPE) was investigated using a thermogravimetric analysis (TGA) system at various heating rates of 2, 10, 20 and 50 K/min in the temperature range of 300-1273 K in the nitrogen atmosphere. Kissinger-Akahira-Sunose, Friedman, Flynn-Wall-Ozawa and Coats-Redfern methods have been used to determine activation energies of materials degradation. The analysis of the process mechanism by Criado and Coats-Redfern methods showed the following: the mec… Show more

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Cited by 21 publications
(3 citation statements)
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“…where g(x) is the integrated form of the conversion function f(x). According to the reaction mechanism, this function, g(x), is commonly given in literature [15] [16]. Table 2 summarizes all possible functions and mechanisms.…”
Section: Kinetic Approachmentioning
confidence: 99%
“…where g(x) is the integrated form of the conversion function f(x). According to the reaction mechanism, this function, g(x), is commonly given in literature [15] [16]. Table 2 summarizes all possible functions and mechanisms.…”
Section: Kinetic Approachmentioning
confidence: 99%
“…Reaction mechanisms and their algebraic expressions f(x) and g(x) most commonly given in literature [23] for the description of solid state reactions are listed in Table 3.…”
Section: Kinetic Studymentioning
confidence: 99%
“…Information about the kinetics of the pyrolysis process is important when designing industrial pyrolysis plants. The kinetics of co-pyrolysis of polymer waste with various materials containing organic matter is well studied. , Thus, Aboulkas et al have studied pyrolysis kinetics of Moroccan oil shale kerogen mixed with high-density polyethylene (PE-HD) using a thermogravimetric analysis (TGA) system at various heating rates of 2, 10, 20, and 50 K/min in the temperature range of 300–1273 K in a nitrogen atmosphere. The thermogravimetric method was extended by the same group to the studies on the pyrolytic behaviors of Moroccan oil shale kerogen, polyethylene terephthalate, and their mixtures.…”
Section: Introductionmentioning
confidence: 99%