Kinetics and Thermodynamics of Formation and Electron‐Transfer Reactions of Surfactant Cobalt(III) Complexes Containing Polypyridyl Ligands with Fe(CN)64−in Microheterogeneous Environment
Abstract:The electron‐transfer reaction of some surfactant cobalt(III) complexes, cis‐[Co(ip)2(C12H25NH2)2]3+ 1, cis‐[Co(dpq)2(C12H25NH2)2]3+ 2, and cis‐[Co(dpqc)2(C12H25NH2)2]3+ 3 (ip = imidazo[4,5‐f][1,10]phenanthroline, dpq = dipyrido[3,2‐d:2′‐3′‐f]quinoxaline, dpqc = dipyrido[3,2‐a:2′,4′‐c](6,7,8,9‐tetrahydro)phenazine, C12H25NH2 = dodecylamine) with the Fe(CN)64− ion has been investigated in microheterogeneous media (micelles, β‐cyclodextrin) at different temperatures by the spectrophotometric method under pseudo‐… Show more
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