Kinetics and mechanism of the oxidation of 2-furancarbox-aldehyde by thallium(III) in perchloric acid solutions

Kumar, Dinesh; Rani, Ashu; Prasad, D. S. N.; Gupta, K. C.

doi:10.1007/bf02075424

Cited by 3 publications

(1 citation statement)

References 7 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The excess of ferrous ammonium sulphate was titrated against a standard solution of ceric sulphate using ferroin as an indictor. The concentration of ceric perchlorate at various time intervals was determined by the method described by Szaleo [17].…”

Section: Methodsmentioning

confidence: 99%

Oxidation of Crotonic Acid With Ce (Iv) Perchlorates

Ic¹,

Shukla²,

Rani³

2012

Int J of Chem Res

View full text Add to dashboard Cite

The present manuscript deals the kinetics and mechanism of the reaction between crotonic acid and ceric perchlorates. The order of the reaction with respect to Ce (IV) is unity but the rate is dependent on the initial concentration of the Ce (IV). The spectrophotometric investigation has been also carried out which negatived the intermediate complex formation. The main reaction species of Ce (IV) involved in rate determining step was the hydrated uncomplexed ceric ion which at higher initial concentration gets dimerises.

show abstract

Section: Methodsmentioning

confidence: 99%

Oxidation of Crotonic Acid With Ce (Iv) Perchlorates

Ic¹,

Shukla²,

Rani³

2012

Int J of Chem Res

View full text Add to dashboard Cite

show abstract

Oxidation of substituted 2‐furaldehydes by quinolinium dichromate: a kinetic study

Chaubey

Kharsyntiew

Mahanti

2003

J of Physical Organic Chem

View full text Add to dashboard Cite

The kinetics of oxidation of substituted 2‐furaldehydes by quinolinium dichromate in sulfuric acid, using 50% acetic acid as the solvent, was studied. The rate of the reaction was first order in each of the substrate, oxidant and acid. The kinetic data are discussed with reference to the aldehyde hydration equilibria. The kinetic results support a mechanistic pathway proceeding via a rate‐determining oxidative decomposition of the chromate ester of the aldehyde hydrate. Copyright © 2003 John Wiley & Sons, Ltd.

show abstract

Kinetics of the Oxidation of Heterocyclic Aldehydes by Quinolinium Dichromate

Chaubey¹,

Das²,

Mahanti³

2002

Bulletin of the Chemical Society of Japan

View full text Add to dashboard Cite

Quinolinium dichromate in sulfuric acid oxidizes heterocyclic aldehydes (2-furaldehyde, 2-pyrrolecarbaldehyde, 2-thiophenecarbaldehyde) to the corresponding acids in a 50% (v/v) acetic acid–water medium. The kinetic data on the rates of oxidation of the substrates have been discussed with reference to the aldehyde hydration equilibria. The kinetic results support a mechanistic pathway proceeding via a rate-determining oxidative decomposition of the chromate ester of the aldehyde hydrate.

show abstract

Kinetics and mechanism of the oxidation of 2-furancarbox-aldehyde by thallium(III) in perchloric acid solutions

Cited by 3 publications

References 7 publications

Oxidation of Crotonic Acid With Ce (Iv) Perchlorates

Oxidation of Crotonic Acid With Ce (Iv) Perchlorates

Oxidation of substituted 2‐furaldehydes by quinolinium dichromate: a kinetic study

Kinetics of the Oxidation of Heterocyclic Aldehydes by Quinolinium Dichromate

Contact Info

Product

Resources

About