Kinetics and mechanism of halide exchange in reactions of CpRu(PPh<sub>3</sub>)<sub>2</sub>Cl with alkyl halides: evidence for radical pairs

Carney, Katherine; Polito, Lauren; Reid, Kamilya; Srinivasan, Surbhi; Blake, Gabrielle; Chintala, Nithin; Dong, Sijia S.; Kirss, Rein U.

doi:10.1039/d3nj03839d

New J. Chem.

2023

DOI: 10.1039/d3nj03839d

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Kinetics and mechanism of halide exchange in reactions of CpRu(PPh₃)₂Cl with alkyl halides: evidence for radical pairs

Katherine Carney,

Lauren Polito,

Kamilya Reid

et al.

Abstract: Halide exchange reactions between CpRu(PPh3)2Cl (1) and CBr4, CHBr3, CBr3CO2Et or CHBr2CO2Et yielding CpRu(PPh3)2Br (3) are facile and appear to proceed by a radical pair intermediate in a second order reaction.

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Kinetics and mechanism of halide exchange in reactions of CpRu(PPh₃)₂Cl with alkyl halides: evidence for radical pairs

Abstract: Halide exchange reactions between CpRu(PPh3)2Cl (1) and CBr4, CHBr3, CBr3CO2Et or CHBr2CO2Et yielding CpRu(PPh3)2Br (3) are facile and appear to proceed by a radical pair intermediate in a second order reaction.

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References 38 publications

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Kinetics and mechanism of halide exchange in reactions of CpRu(PPh3)2Cl with alkyl halides: evidence for radical pairs

Abstract: Halide exchange reactions between CpRu(PPh3)2Cl (1) and CBr4, CHBr3, CBr3CO2Et or CHBr2CO2Et yielding CpRu(PPh3)2Br (3) are facile and appear to proceed by a radical pair intermediate in a second order reaction.

Cited by 0 publications

References 38 publications

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Kinetics and mechanism of halide exchange in reactions of CpRu(PPh₃)₂Cl with alkyl halides: evidence for radical pairs