Kinetics and Mechanism of Alkaline Hydrolysis of N-(o-Aminophenyl)Phthalimide in the Presence and Absence of Cationic Micelles and Sodium Salts of Aliphatic Acids
Abstract:Pseudo first-order rate constants, k obs, for the alkaline hydrolysis of N-( o-aminophenyl) phthalimide, obtained at constant [CTABr]T (total concentration of cetyltrimethylammonium bromide) and varying concentrations of inert salt MX (MX = sodium formate, sodium acetate, sodium propanoate, sodium butyrate, sodium valerate and sodium hexanoate) follow the relationship: [Formula: see text], where θ and KX/S are empirical constants and S = HO-. The values of KX/S for each aliphatic acid decrease with an increase… Show more
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