Kinetic Study of Oxidation of Trichloroethylene by Potassium Permanganate

Huang, Kun-Chang; Hoag, George E.; Chheda, Pradeep; Woody, Bernard A.; Dobbs, Gregory M.

doi:10.1089/ees.1999.16.265

Cited by 70 publications

(39 citation statements)

References 9 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…A number of review articles provide insight into the chemistry and proper application of oxidation regimens (Gates and Siegrist 1995;Kubal et al 2008;Rivas 2006;Seol et al 2003;Tsai et al 2008;Watts and Teel 2005). ISCO has been successfully used to oxidize and thus lower the concentration of petroleum-derived hydrocarbons (total petroleum hydrocarbons, TPH, Crimi and Taylor 2007;Gates and Siegrist 1995;Huang et al 2005;Jung et al 2005;Lee and Kim 2002), polyaromatic hydrocarbons (PAH; Lee and Hosomi 2001;Masten and Davies 1997;Nam et al 2001;Watts et al 2002), and chlorinated hydrocarbons (Huang et al 1999(Huang et al , 2005Hunkeler et al 2003;Northup and Cassidy 2008;Ormad et al 1994;Schnarr et al 1998;Siegrist et al 1999;Vella and Veronda 1993;Watts et al 1990). ISCO is a versatile remediation strategy, providing rapid and extensive removal of both light and dense recalcitrant compounds in pure phase.…”

Section: Introductionmentioning

confidence: 99%

Efforts to improve coupled in situ chemical oxidation with bioremediation: a review of optimization strategies

et al. 2010

View full text Add to dashboard Cite

Purpose In order to provide highly effective yet relatively inexpensive strategies for the remediation of recalcitrant organic contaminants, research has focused on in situ treatment technologies. Recent investigation has shown that coupling two common treatments-in situ chemical oxidation (ISCO) and in situ bioremediation-is not only feasible but in many cases provides more efficient and extensive cleanup of contaminated subsurfaces. However, the combination of aggressive chemical oxidants with delicate microbial activity requires a thorough understanding of the impact of each step on soil geochemistry, biota, and contaminant dynamics. In an attempt to optimize coupled chemical and biological remediation, investigations have focused on elucidating parameters that are necessary to successful treatment. In the case of ISCO, the impacts of chemical oxidant type and quantity on bacterial populations and contaminant biodegradability have been considered. Similarly, biostimulation, that is, the adjustment of redox conditions and amendment with electron donors, acceptors, and nutrients, and bioaugmentation have been used to expedite the regeneration of biodegradation following oxidation. The purpose of this review is to integrate recent results on coupled ISCO and bioremediation with the goal of identifying parameters necessary to an optimized biphasic treatment and areas that require additional focus. Conclusions and recommendations Although a biphasic treatment consisting of ISCO and bioremediation is a feasible in situ remediation technology, a thorough understanding of the impact of chemical oxidation on subsequent microbial activity is required. Such an understanding is essential as coupled chemical and biological remediation technologies are further optimized.

show abstract

Section: Introductionmentioning

confidence: 99%

Efforts to improve coupled in situ chemical oxidation with bioremediation: a review of optimization strategies

et al. 2010

View full text Add to dashboard Cite

show abstract

“…Of those oxidations of organic compounds with permanganate, the reactions between alkenes and permanganate have been extensively studied (Wiberg and Geer, 1966;Freeman and Kappos, 1985;Ogino and Kikuiri, 1989;Huang et al, 1999;Schwartz, 1999, 2000;Huang et al, 2002). MCRR has diene function group at ADDA side chain, so presumably the MCRR-permanganate reactions will proceed in similar pathways to the reactions of alkenes with permanganate.…”

Section: Introductionmentioning

confidence: 99%

Kinetics of the oxidation of MCRR by potassium permanganate

Chen

Xiao

Liu

et al. 2005

Toxicon

View full text Add to dashboard Cite

“…In situ chemical oxidation (ISCO) is becoming increasingly popular for remediating organics in soil and groundwater (Vella & Veronda, 1994;Gates et al, 1995;Schnarr et al, 1998;West et al, 1998;Huang et al, 1999;Siegrist et al, 1999;Gates-Anderson et al, 2001;Lowe et al, 2002;Struse et al, 2002). Proper design of a field-scale implementation of ISCO requires data on target contaminant levels as well as quantitative estimates of other oxidant sinks.…”

Section: Introductionmentioning

confidence: 99%