The additional processes of excitation of B 2E 2 state of HgBr and HgCI excimer molecules in gas-discharge plasma on HgBr2/HgCI2/He and HgBr2/HgCI2/N2/He mixtures have been investigated (together with dissociation of mercury dihalides by electronic shock, which is the basic process). The pumping of working mixtures was implemented by highfrequency (f= 1000 Hz) barrier and surface discharges ofnanosecond duration (1OO ns), taking place simultaneously.The essential increase in the amplitude (up to 3 times), radiation pulse duration (up to 2 times) and their back edge (up to 15 times) has been revealed with the addition of molecular nitrogen in the HgBr2/HgC12/He working mixture, and also the difference in value of amplitudes of the first, second and third pulses have been revealed. Tt has been established, that the change in temporary radiation parameters is caused by the transfer of energy from molecular nitrogen in metastable state A3EU at collisions with molecules of mercury dihalides. One more additional process, increasing the amplitude of the second and third radiation pulses both in the HgBr2/HgCl2/He mixtures, and in the . .. .
2+
. . 2±HgBr2/HgCl2/N2/He mixtures is the excitation of the HgBr(X I 1/2) and HgCl(X I , 2) radicals in the B E 2 -state by the electrons.