“…Past literature has extensively addressed thermochemical degradation and combustion of carbon rich solid materials (solid fuels), including coals [1][2][3][4][5][6][7][8][9][10], biomass [11][12][13][14][15][16][17][18][19][20][21][22][23][24][25] and polymers [26][27][28][29][30][31][32][33][34][35][36][37], as a possible route to the production of energy and/or of valuable chemicals. As a matter of fact most studies are focused on pyrolysis under inert conditions and on combustion of the residual char, although in practical applications thermal degradation of solid fuels often occurs in presence of oxygen.…”