Kinetic models for the thermal cracking of Athabasca bitumen

Phillips, Colin R.; Haidar, Nagib I.; Poon, Yiu Cheong

doi:10.1016/0016-2361(85)90055-9

Cited by 109 publications

(69 citation statements)

References 4 publications

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“…LC as defined in our model is initially present as a higher fraction (16 wt%) compared to the 10.3 wt% given by Phillips et al 16 .…”

Section: Pvt Data: the Peng-robinson Equation Of State (Pr-eos) Availmentioning

confidence: 48%

“…The Phillips et al 16 thermal cracking kinetics scheme, together with PVT data estimated using the PR-EOS, have been used to develop a more accurate numerical simulation of the Xia and Greaves 8 3D…”

Section: Discussionmentioning

confidence: 99%

“…However, the PVT data for the individual pseudo-components was generated separately, since this was not reported by Philips et al 16 .…”

Section: Methodsmentioning

confidence: 99%

“…1) based on the initial boiling point (IBP) data provided by Phillips et al 16 . The pseudo-components and PVT data is given in Tab.…”

Section: Pvt Data: the Peng-robinson Equation Of State (Pr-eos) Availmentioning

confidence: 99%

“…al. 16 direct conversion cracking kinetics scheme. It is found that this kinetics scheme results in a significant decrease in the uncertainty in the simulation results, as it does not depend on the stoichiometry of the products.…”

mentioning

confidence: 99%

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Dynamic Simulation of the Toe-to-Heel Air Injection Heavy Oil Recovery Process

2017

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Toe-to-Heel Air Injection (THAI) is a variant of conventional In-Situ Combustion (ISC) that uses a horizontal production well to recover mobilised partially upgraded heavy oil. It has a number of advantages over other heavy oil recovery techniques such as high recovery potential. However, existing models are unable to predict the effect of the most important operational parameters, such as fuel availability and produced oxygen concentration, which will give rise to unsafe designs. Therefore, we have developed a new model that accurately predicts dynamic conditions in the reservoir and also is easily scalable to investigate different field scenarios. The model used a three component direct conversion cracking kinetics scheme, which does not depend on the stoichiometry of the products and, thus, reduces the extent of uncertainty in the simulation results as the number of unknowns is reduced.The oil production rate and cumulative oil produced were well predicted, with the latter deviating from the experimental value by only 4%. The improved ability of the model to emulate real process dynamics meant it also accurately predicted when the oxygen was first produced, thereby enabling a more accurate assessment to be made of when it would be safe to shut-in the process, prior to oxygen breakthrough occurring. The increasing trend in produced oxygen concentration following a step change in the injected oxygen rate by 33 % was closely replicated by the model. The new simulations have now elucidated the mechanism of oxygen production during the later stages of the experiment.The model has allowed limits to be placed on the air injection rates that ensure stability of operation.Unlike previous models, the new simulations have provided better quantitative prediction of fuel laydown, which is a key phenomenon that determines whether, or not, successful operation of the THAI process can be achieved. The new model has also shown that, for completely stable operation, 2 2 the combustion zone must be restricted to the upper portion of the sand pack, which can be achieved by using higher producer back pressure.

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“…LC as defined in our model is initially present as a higher fraction (16 wt%) compared to the 10.3 wt% given by Phillips et al 16 .…”

Section: Pvt Data: the Peng-robinson Equation Of State (Pr-eos) Availmentioning

confidence: 48%

Section: Discussionmentioning

confidence: 99%

“…However, the PVT data for the individual pseudo-components was generated separately, since this was not reported by Philips et al 16 .…”

Section: Methodsmentioning

confidence: 99%

“…1) based on the initial boiling point (IBP) data provided by Phillips et al 16 . The pseudo-components and PVT data is given in Tab.…”

Section: Pvt Data: the Peng-robinson Equation Of State (Pr-eos) Availmentioning

confidence: 99%