volume 159, issue 1, P130-141 2012
DOI: 10.1016/j.combustflame.2011.06.019
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Abstract: A detailed chemical–kinetic mechanism is used to predict critical conditions of extinction and autoignition of condensed hydrocarbon fuels in non-premixed flows. The mechanism includes reactions that describe ‘‘low temperature chemistry’’ as well as ‘‘high temperature chemistry’’ for many high molecular weight fuels. The fuels considered here are n-heptane, n-decane, n-dodecane, n-hexadecane, and isooctane. The kinetic model is validated by comparing its predictions of critical conditions of extinction and aut…

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