1977
DOI: 10.1016/0032-3950(77)90018-1
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Kinetic features of the photoreduction of ferric chloride in solid polymethylmethacrylate

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Cited by 4 publications
(2 citation statements)
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“…The possibility of obtaining spin-labelled rubbers by interaction of their solutions in the inert solvents with the mixture of nitrogen dioxide and oxygen has been demonstrated in the work [34]. Such rubbers can be prepared simply and rapidly by reactions of block polymeric samples with gaseous NO 2 [35]. The experiments were carried out on 1,4-cis-polyisoprene (PI) and copolymer of ethylene, propylene and dicyclopentadiene.…”
Section: Preparation Of Spin-labelled Rubbersmentioning
confidence: 99%
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“…The possibility of obtaining spin-labelled rubbers by interaction of their solutions in the inert solvents with the mixture of nitrogen dioxide and oxygen has been demonstrated in the work [34]. Such rubbers can be prepared simply and rapidly by reactions of block polymeric samples with gaseous NO 2 [35]. The experiments were carried out on 1,4-cis-polyisoprene (PI) and copolymer of ethylene, propylene and dicyclopentadiene.…”
Section: Preparation Of Spin-labelled Rubbersmentioning
confidence: 99%
“…Reactions (35) at durable exposure lead to practically full disappearance of -NH-groups in macromolecules. Amidyl macroradicals leaving the cage are decomposed with breaking the main chain and can also be converted into N-nitrite by recombination with the monomer form of NO 2 .…”
Section: Experimental Confirmations Of Ion-radical Mechanism Of Polymers Nitrosationmentioning
confidence: 99%