1982
DOI: 10.1021/ja00366a046
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Kinetic determination of transition metal-alkyl bond dissociation energies: application to organocobalt compounds related to B12 coenzymes

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Cited by 148 publications
(77 citation statements)
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“…[1][2][3][4][5][6][7][8] Reactions of organic radicals (CCA C H T U N G T R E N N U N G (CH 3 )(X)R) with metalcentered radicals either produce an organometallic complex ([M À CA C H T U N G T R E N N U N G (CH 3 )(X)R]) or a metal hydride ([M À H]) and an olefin (CH 2 =C(X)R) by the metallo-radical abstracting a bhydrogen from the organic radical CCA C H T U N G T R E N N U N G (CH 3 )(X)R (Scheme 1a). [9] Abstract: The mechanisms for hydrogen-atom transfer from the cyanoisopropyl radical CCA C H T U N G T R E N N U N G (CH 3 ) 2 CN to [Co …”
Section: Reactions Of Metal-centered Radicals ([M]c) and Organometal supporting
confidence: 44%
“…[1][2][3][4][5][6][7][8] Reactions of organic radicals (CCA C H T U N G T R E N N U N G (CH 3 )(X)R) with metalcentered radicals either produce an organometallic complex ([M À CA C H T U N G T R E N N U N G (CH 3 )(X)R]) or a metal hydride ([M À H]) and an olefin (CH 2 =C(X)R) by the metallo-radical abstracting a bhydrogen from the organic radical CCA C H T U N G T R E N N U N G (CH 3 )(X)R (Scheme 1a). [9] Abstract: The mechanisms for hydrogen-atom transfer from the cyanoisopropyl radical CCA C H T U N G T R E N N U N G (CH 3 ) 2 CN to [Co …”
Section: Reactions Of Metal-centered Radicals ([M]c) and Organometal supporting
confidence: 44%
“…[3,4]. Inaddition, they are also used asmodels of reaction centers of metalloenzymes [5,6], and nonlinearopticalmaterials [7]. Moreover,inbiologicaland artificialsystems allosteric regulation is effective in controlling molecularf unctions, such asm olecularr ecognition and biological activity [8].…”
Section: Discussionsupporting
confidence: 45%
“…These compounds can easily form metallosalen complexes, and some of them show excellent catalytic activities for epoxidation and aziridination [3,4]. In addition, they are also used as models of reaction centers of metalloenzymes [5,6], and nonlinear optical materials [7]. Moreover, in biological and artificial systems allosteric regulation is effective in controlling molecular functions, such as molecular recognition and biological activity [8].…”
Section: Discussionsupporting
confidence: 41%