2022
DOI: 10.1002/ange.202211812
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Kinetic Co‐assembly Pathway Induced Chirality Inversion Along with Morphology Transition

Abstract: Kinetic co-assembly pathway induced chirality inversion along with morphology transition is of importance to understand biological processes, but still remains a challenge to realize in artificial systems. Herein, helical nanofibers consisting of phenylalaninebased enantiomers (L/DPF) successfully transform into kinetically trapped architectures with opposite helicity through a kinetic co-assembly pathway. By contrast, the co-assemblies obtained by a thermodynamic pathway exhibit non-helical structures. The fo… Show more

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