Kinetic Analysis of the Non‐Monotonic Response of Ethene Hydrogenation Rates to Ceria Surface Reduction
Sadia Afrin,
Praveen Bollini
Abstract:The precise effect of oxide understoichiometry on bulk oxide catalytic properties continues to remain a subject of intense investigation. Of specific interest in this regard is the role of oxygen vacancies present on bulk ceria catalysts that have recently been reported to represent a more cost‐effective alternative to the more toxic and expensive catalysts used industrially for the selective hydrogenation of acetylene to ethylene. Contrasting claims as to the effect of surface reduction on hydrogenation rates… Show more
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