“…4d, bridging sulfur (S0 B) and terminal sulfur (S-1 T) can be observed at 163.9 and 162.5 eV, respectively. 38 Additionally, surface terminal groups reacted with soluble LiPSs to form favorable thiosulfate complexes, which not only helped to inhibit the shuttle effect but also facilitated the catalytic conversion of LiPSs. 39 To further verify the anchoring ability of Ti 3 C 2 @N-CNTs to LiPSs, first-principles calculations based on density functional theory (DFT) were performed.…”