We present the results of NH 3 (1,1), (2,2) and (3,3) and H 2 O maser simultaneous mapping observations toward the high-mass star-forming region W33 with the Nobeyama 45-m radio telescope. W33 has six dust clumps and one of which, W33 Main, is associated with a compact HII region. To investigate star-forming feedback activity on its surroundings, the spatial distribution of the physical parameters was established. The distribution of the rotational temperature shows a systematic change from west to east in our observed region. The hightemperature region obtained in the region near W33 Main is consistent with interaction between the compact HII region and the periphery molecular gas. The size of the interaction area is estimated to be approximately 1.25 pc. NH 3 absorption features are detected toward the centre of the HII region. Interestingly, the absorption feature was detected only in the NH 3 (1,1) and (2,2) transitions, with no absorption feature seen in the (3,3) transition. These complex profiles in NH 3 are difficult to explain by a simple model and may suggest that the gas distribution around the HII region is highly complicated.