Large-scale environmental remediation of polluted water
requires
an effective and recyclable adsorbent produced from an abundant, low-cost,
and renewable feedstock via a simple processing procedure. In this
work, we demonstrate that lignin-derived magnetic activated carbons
(mACs) uniquely satisfy these five criteria for (i) high-performance
adsorption, (ii) high regeneration efficiency, (iii) feedstock economic
and environmental viability, (iv) single-step processing, and (v)
large-scale production. The mACs are synthesized via an efficient
cocarbonization and activation with simultaneous impregnation of ferric
sulfate. The Langmuir model closely fits the adsorption of methylene
blue (MB) by mACs within the temperature range of 298–323 K,
where the adsorption capacity increases as temperature increases.
This capacity increased from 55.0 mg g–1 to 220.2
mg g–1 with the presence of magnetic nanoparticles.
In addition, the magnetite nanoparticles on the activated carbon surface
significantly improve its recycling ability with a removal percentage
above 95% after four cycles for 5:1 mAC.