Kernel Regulation of Ultra‐stable Cu12 Nanoclusters by Triple Collaborative Ligands
Pingting Ye,
Hao Zhang,
Shengchang Xiang
et al.
Abstract:Cu clusters are generally unstable and their cluster nuclei are difficult to be controlled. Even minor adjustments in the synthesis of Cu clusters can easily lead to great changes in their cluster nuclei. In this work, we have successfully utilized triple collaborative ligands to obtain a pair of infinitely extended Cu12 cluster‐based chains (Cu12‐1 and Cu12‐2). They have identical Cu12 metal core structures but slightly different coordinated ligands. Both Cu12‐1 and Cu12‐2 show excellent thermal and ambient s… Show more
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