Simultaneous irradiation of large samples is a special feature of the of neutron activation analysis with radionuclide neutron sources (RNS). Along with working out methodical and technical improvements in this field we have also investigated physical aspects of the analysis with RNS, factors influencing the accuracy of analysis and worked out methods and means of their evaluation. The solution the problem of calibrating the individual irradiation positions for the simultaneous irradiation as well as the problems of accuracy of analysis concerning the absorption and reflection of neutrons are discussed in this paper.
I. The problem of the irradiation positions calibration and determination of the position coefficients for multi-element analysis for a simultaneous irradiation of a group of samplesFor the single-element analysis (for example of gold) with the simultaneous irradiation of a group of samples the coefficients characterizing different distances of the irradiation positions from the source (the so-called position coefficients) have to be determined by irradiating samples with an equal content of gold, measuring the gold line intensity for samples from each position, and normalizing to the gold line intensity of the sample nearest to the source.[1].The set-up of the irradiation assembly in the californium source and the position coefficients used for determination of gold [2] are illustrated in Fig. 1.The 54 irradiation position are characterized by six values of position coefficients (three coefficients for the middle layer and three for the upper and lower layers) given by the distance from the source. They are distinguished by indexes I, II, III (middle layer) and 1,2,3 (upper and lower layers).When performing the multielement analysis, a problem arises: is it possible to use the position coefficients determined for one element (e.g., gold) for the determination of another element in the same samples? Or, are position coefficients different for different elements (nuclides) and if they are, how much and why?Because the spectrum of neutrons depends on the distance from the source and the activation parameters of different nuclides (resonance integrals, activation cross sections for thermal neutrons and their ratios) are different and because the degree of the activation decrease (gradient) depends on the distance and can vary for different nuclides, the position coefficients for other elements need not be the same as those for gold.Experimental determination of these coefficients is rather laborious and it can be difficult to obtain them for various nuclides if the differences are small.The detailed investigation of this problem allowed us to understand better the relationship between the position coefficients, the activation parameters of nuclides