“…As a promising alternative to lead zirconate titanate (PZT), the K 0.5 Na 0.5 NbO 3 , a leadfree ferroelectric material, has exhibited outstanding piezoelectric performance near the polymorphic phase boundary (PPB) [7] and attracted massive attention worldwide in recent years due to its environmental friendliness [8][9][10][11][12][13]. Owing to its unique merits of a high piezoelectric coefficient (d 33 ), excellent ferroelectric properties, and a high Curie temperature (Tc = 420 • C), KNN has been widely utilized in energy-harvesting devices, transducers, actuators, and sensors [14][15][16][17][18][19][20][21]. Although pristine KNN ceramics possess relatively low piezoelectricity (d 33~8 0 pC/N), they can be remarkably improved by tuning sintering conditions [22], domain engineering [23], phase boundary engineering [24,25], texturing [26], and so on.…”