This
paper integrated the life cycle assessment (LCA) approach
with a geographical information system (GIS) in order to compare greenhouse
gas (GHG) emissions in the enhanced oil recovery (EOR) process, utilizing
carbon dioxide (CO2) from three industrial pathways. Pathway
1 is a corn-based ethanol plant with carbon capture and sequestration
(CCS), while pathways 2 and 3 are coal-fired and natural gas-fired
power plants, respectively, with amine-based postcombustion CCS technology.
The pathways were compared to a conventional crude recovery, transport,
refinement, and end-use combustion baseline, which had net GHG emissions
of 0.47 tCO2-e/bbl. Overall, net GHG emissions from pathways
1, 2, and 3 were lower than in the baseline case. In this LCA study,
the system expansion approach was applied and the results indicated
that ethanol-based CCS-EOR was notably the better alternative. However,
the CO2 supply from ethanol plants is limited; they would
have the capacity to produce only about 25 000 bbl/d, compared
to 1.1 Mbbl/d in pathway 2 and 125 000 bbl/d in pathway 3.
Among the system processes assessed, the CO2 injection
system process has the greatest influence on the LCA results, where
the magnitude of the reduction in GHGs depends on each site’s
specific crude recovery rate and that determines the extent of the
displacement credits for coproducts. This finding indicates that crude
oil with lower carbon intensity can be produced from EOR reservoirs
that are less efficient in terms of crude recovered per ton of CO2 injected. However, it should be acknowledged that using less
efficient reservoirs would be associated with greater CO2 supply which has a parasitic energy requirement and would in turn
entail a higher cost burden.