Joule-heating electrospun reduced-graphene oxide nanoribbon-coated reusable polymeric sorbent with an excellent sorption/desorption of high-viscosity oils
“…One strategy is to reduce the oil viscosity by heating up to increase fluidity. 13,21,22 For example, Huang et al proposed a reduced graphene oxide-coated wood sponge (F-rGO@WS) modified by fluoroalkyl silane, which utilized the electrothermal capacity of rGO to improve crude oil flow. 23 Chao et al made a wood sponge decorated with rGO that utilized a photothermal effect to rapidly reduce viscosity, reaching temperatures as high as 88 °C in 100 s. 24 Nevertheless, the electrothermal conversion requires an additional power supply, which is unreliable in complex marine environments, and the photothermal effect may not be effective in poor lighting conditions.…”
Section: Introductionmentioning
confidence: 99%
“…However, the chemical industry generated a lot of high-viscosity oil pollutants, and most of the published literature had few research studies on the separation of high-viscosity oil (>300 mPa·s) and water, especially crude oil/water, which was always seriously contaminated with materials due to its extremely strong adhesion, making the separation difficult. − In recent years, some advanced adsorbent materials and membrane materials have gradually appeared for the separation of high-viscosity crude oil and water. − According to our survey, there are two main treatment strategies. One strategy is to reduce the oil viscosity by heating up to increase fluidity. ,, For example, Huang et al proposed a reduced graphene oxide-coated wood sponge (F-rGO@WS) modified by fluoroalkyl silane, which utilized the electrothermal capacity of rGO to improve crude oil flow . Chao et al made a wood sponge decorated with rGO that utilized a photothermal effect to rapidly reduce viscosity, reaching temperatures as high as 88 °C in 100 s .…”
Superhydrophilic materials, renowned for their capacity to establish a hydration layer that effectively mitigates oil pollution, have garnered considerable attention for oil−water separation. However, these materials have difficulties in separating water from high-viscosity oils, which can easily adhere to the surfaces of the materials, resulting in reduced separation efficiencies. In this work, a superhydrophilic wood-based cellulose aerogel coated with a protonated nanocomposite chitosan coating (PPNC-CS) was proposed to enhance water affinity and prevent viscous oil adhesion. The separation efficiency of the prepared cellulose aerogel@PPNC-CS reached an impressive 99.90% for high-viscosity crude oil and water. Notably, it exhibited an underwater−oil contact angle exceeding 160°, oil contamination prevention, and self-cleaning performances. These properties can be attributed to the presence of micronanoscale coating particles on the lamellar architecture of the cellulose aerogel@PPNC-CS, coupled with the formation of a robust hydration layer through electrostatic interaction and hydrogen bonding. Moreover, it exhibited enduring chemical stability, resistance to acid and alkali corrosion, and a notable capacity for high-concentration salt tolerance. This research introduces a promising material for the sustainable purification of aqueous viscous oils, offering low cost and environmental friendliness.
“…One strategy is to reduce the oil viscosity by heating up to increase fluidity. 13,21,22 For example, Huang et al proposed a reduced graphene oxide-coated wood sponge (F-rGO@WS) modified by fluoroalkyl silane, which utilized the electrothermal capacity of rGO to improve crude oil flow. 23 Chao et al made a wood sponge decorated with rGO that utilized a photothermal effect to rapidly reduce viscosity, reaching temperatures as high as 88 °C in 100 s. 24 Nevertheless, the electrothermal conversion requires an additional power supply, which is unreliable in complex marine environments, and the photothermal effect may not be effective in poor lighting conditions.…”
Section: Introductionmentioning
confidence: 99%
“…However, the chemical industry generated a lot of high-viscosity oil pollutants, and most of the published literature had few research studies on the separation of high-viscosity oil (>300 mPa·s) and water, especially crude oil/water, which was always seriously contaminated with materials due to its extremely strong adhesion, making the separation difficult. − In recent years, some advanced adsorbent materials and membrane materials have gradually appeared for the separation of high-viscosity crude oil and water. − According to our survey, there are two main treatment strategies. One strategy is to reduce the oil viscosity by heating up to increase fluidity. ,, For example, Huang et al proposed a reduced graphene oxide-coated wood sponge (F-rGO@WS) modified by fluoroalkyl silane, which utilized the electrothermal capacity of rGO to improve crude oil flow . Chao et al made a wood sponge decorated with rGO that utilized a photothermal effect to rapidly reduce viscosity, reaching temperatures as high as 88 °C in 100 s .…”
Superhydrophilic materials, renowned for their capacity to establish a hydration layer that effectively mitigates oil pollution, have garnered considerable attention for oil−water separation. However, these materials have difficulties in separating water from high-viscosity oils, which can easily adhere to the surfaces of the materials, resulting in reduced separation efficiencies. In this work, a superhydrophilic wood-based cellulose aerogel coated with a protonated nanocomposite chitosan coating (PPNC-CS) was proposed to enhance water affinity and prevent viscous oil adhesion. The separation efficiency of the prepared cellulose aerogel@PPNC-CS reached an impressive 99.90% for high-viscosity crude oil and water. Notably, it exhibited an underwater−oil contact angle exceeding 160°, oil contamination prevention, and self-cleaning performances. These properties can be attributed to the presence of micronanoscale coating particles on the lamellar architecture of the cellulose aerogel@PPNC-CS, coupled with the formation of a robust hydration layer through electrostatic interaction and hydrogen bonding. Moreover, it exhibited enduring chemical stability, resistance to acid and alkali corrosion, and a notable capacity for high-concentration salt tolerance. This research introduces a promising material for the sustainable purification of aqueous viscous oils, offering low cost and environmental friendliness.
“…As global industries expand rapidly, the severity of water pollution is escalating. , Among various pollutants, water-insoluble oils and water-soluble organic dyes are viewed as the primary contaminants in wastewater, posing significant threats to both the environment and human health. − So far, numerous technologies, including adsorption, − photocatalysis, − chemical oxidation, , biological methods, ion exchange, and membrane separation − have been undertaken to address oil–water separation and dye removal from wastewater. Noteworthily, owing to the increasing complexity of wastewater, traditional single-treatment technology has become inadequate for meeting current demands. − Fortunately, membrane adsorption–separation technology has recently emerged as an effective method for treating complex wastewater containing oil and dyes. − This method combines the benefits of adsorption and membrane separation, providing advantages like simple operation, low energy usage, and high efficiency. ,, Based on this, numerous membranes have been developed with special wettability, particularly superhydrophilic and underwater superoleophobic features, along with abundant adsorption sites for simultaneously removing dyes and separating oil–water mixtures. ,− However, the majority of these adsorption–separation membranes are made from nonrenewable resources and are nonbiodegradable, potentially causing secondary environmental pollution after their service life .…”
Developing a cost-effective, versatile, biodegradable, and biobased membrane is crucial for the sustainable treatment of complex wastewater. In this work, a multifunctional membrane was fabricated from polydopamine-modified waste paper (WP@PDA) and hydrothermal carbonized chitosan (HTCC), through simple vacuum filtration. This membrane demonstrated high efficiency in separating oil-in-water emulsions and allowed for the in situ dye removal under controllable pH conditions. The results showed that the as-prepared WP@PDA/HTCC membrane exhibited superhydrophilic, oil-resistant, and pH-tunable surface charge features. With the weight ratio of WP@PDA and HTCC of 6:2, it displayed optimal mechanical properties and structural stability in aqueous environments. As expected, the WP@PDA/HTCC membrane achieved outstanding performance in separating different oil-in-water emulsions at 0.05 bar followed by the satisfactory flux of approximately 2400 L m −2 h −1 bar −1 and separation efficiency of around 99.5%. Furthermore, the abundant functional groups on the WP@PDA and HTCC surface also endowed this membrane with a high removal capability for both cationic and anionic dyes. It can efficiently eliminate methyl orange (MO) and methylene blue (MEB) from dye-contaminated wastewater mainly through electrostatic interactions. Even after filtering 1550 L m −2 of MO and 1650 L m −2 of MEB simulated wastewater using WP@PDA/ HTCC membrane, its removal efficiencies toward both dyes remained above 90.0%. Interestingly, the WP@PDA/HTCC-1 membrane presented bidirectional controlled dye separation behaviors for the dye mixture under the suitable solution pH due to its pH-tunable surface charge feature. Most importantly, the as-prepared membrane showed excellent reusability and high resistance against harsh chemical corrosions without losing its properties. Therefore, the as-prepared WP@PDA/HTCC-1 membrane could be a promising material for complex wastewater treatment.
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