2021
DOI: 10.1002/chem.202103446
|View full text |Cite
|
Sign up to set email alerts
|

Joint Venture of Metal Cluster and Amphiphilic Cationic Minidendron Resulting in Near Infrared Emissive Lamellar Ionic Liquid Crystals

Abstract: Inorganic red‐NIR emissive materials are particularly relevant in many fields like optoelectronic, bioimaging or solar cells. Benefiting from their emission in devices implies their integration in easy‐to‐handle materials like liquid crystals, whose long‐range ordering and self‐healing abilities could be exploited and influence emission. Herein, we present red‐NIR emissive hybrid materials obtained with phosphorescent octahedral molybdenum cluster anions electrostatically associated with amphiphilic guanidiniu… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
2
1

Citation Types

0
5
0

Year Published

2021
2021
2024
2024

Publication Types

Select...
6

Relationship

3
3

Authors

Journals

citations
Cited by 7 publications
(5 citation statements)
references
References 48 publications
0
5
0
Order By: Relevance
“…The diffraction pattern is characteristic of a columnar hexagonal Col h mesophase with the P6mm symmetry and a lattice parameter of 39.19 Å. In agreement with previous work on clustomesogens, broad peaks at 12.32 and 8.57 Å were observed due to the cluster. As summarized in Table and more detailed in Table S2 (Supporting Information), all other hybrids 12C4–Cl , 12C4–Br , 15C5–Cl , 18C6–Cl , and 18C6–Br exhibited similar Col h phases.…”
Section: Resultsmentioning
confidence: 99%
“…The diffraction pattern is characteristic of a columnar hexagonal Col h mesophase with the P6mm symmetry and a lattice parameter of 39.19 Å. In agreement with previous work on clustomesogens, broad peaks at 12.32 and 8.57 Å were observed due to the cluster. As summarized in Table and more detailed in Table S2 (Supporting Information), all other hybrids 12C4–Cl , 12C4–Br , 15C5–Cl , 18C6–Cl , and 18C6–Br exhibited similar Col h phases.…”
Section: Resultsmentioning
confidence: 99%
“…The guanidinium salts Gua(14)X were prepared via salt metathesis from the known tristetradecyloxyphenylguanidinium chloride Gua(14)Cl 64 according to the procedure proposed by Butschies 18 (Scheme 1). After recrystallization, the resulting guanidinium salts Gua(14)X were isolated in 79–91% yield.…”
Section: Resultsmentioning
confidence: 99%
“…6), which we propose for these wedgeshaped ILCs in agreement with the previous work. 64,69,75,82,83 Details of the XRD data are summarized in Fig. S9-S11 (ESI †).…”
Section: Mesomorphic Properties Of Guanidinium Ilcsmentioning
confidence: 99%
See 2 more Smart Citations