Jansenius, Cornelius d. J.

Leonhardt, Rochus

doi:10.1007/978-3-476-02948-5_105

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Tuning the Properties Of Periodic Mesoporous Organosilica Fi1

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2018

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“…For instance, employing the SAWS results in an YM value which is more representative of the in-plane YM component because acoustic waves propagate parallel to the substrate. [19,20] On the other hand, an NI measurement using a Berkovich tip provides mainly the out-of-plane YM component. [21] Compared to the in-plane components, the YM component normal to the substrate is the weakest in PMO films with a 2D hexagonal pore organization and pores parallel to the substrate.…”

Section: Tuning the Properties Of Periodic Mesoporous Organosilica Fimentioning

confidence: 99%

Tuning the Properties of Periodic Mesoporous Organosilica Films for Low‐k Application by Gemini Surfactants

Redzheb¹,

Okudur

Bernstorff

et al. 2018

ChemPhysChem

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Periodic mesoporous organosilica (PMO) thin films were synthesized by evaporation-induced self-assembly of 1,2-bis(triethoxysilyl)ethane and an ionic Gemini 16-12-16 surfactant under acidic conditions. The films were characterized by Fourier-transform infrared spectroscopy, grazing-incidence small-angle X-ray scattering, ellipsometric porosimetry, impedance measurements, and nanoindentation. The ease of control of the packing parameter in Gemini surfactants makes the PMO film templated by a Gemini an exciting first step towards small pore size PMO films with engineered mesostructures.

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Section: Tuning the Properties Of Periodic Mesoporous Organosilica Fimentioning

confidence: 99%